Book review of “Lanthanide metal-organic frameworks”
نویسنده
چکیده
Metal-organic frameworks (MOFs) are chemical systems comprising organic molecules coordinated to metal ions or clusters to form one-, two-, or three-dimensional structural arrangement (Figure 1). The use of lanthanide (Ln) ions results in a specific class of Ln-MOFs possessing unique physico-chemical properties owing to a large atomic magnetic moment, strong spin-orbital coupling, high coordination number, and abundant coordinationmodes of the Ln ions. Therefore, this research field attracted much attention of a scientific community, hence generating a vast number of research papers and reviews devoted to Ln-MOFs. However, lack of a book addressing exclusively the Ln-MOF systems and covering comprehensively all the major aspects of this research field considerably hinders popularization of this frontier multidisciplinary science as for a general scientific audience and for researchers specializing in other research areas related to MOFs. In connection with this, “Lanthanide Metal-Organic Framework” edited by Peng Cheng fills this gap timely to give an excellent overview of the Ln-MOF systems hence covering the structural diversity, preparation methods, physico-chemical properties, and various applications. In particular, this book consists of nine chapters written by well-known specialists and focuses on all major research topics for Ln-MOFs including synthetic routes for homonuclear, heteronuclear, and nanoscaled complexes, various properties such as porosity, magnetism, chirality, luminescence,
منابع مشابه
Synthesis, Structure and Properties of Lanthanide-Organic Frameworks with Imidazolylmethylisophthalate Ligands
Three new lanthanide-organic frameworks {[Ln(L)(OClO3)(H2O)]·0.5H2O}n [Ln = Sm (1), Eu (2), Er (3)] have been prepared by hydrothermal reactions of the corresponding lanthanide oxide (Ln2O3), silver perchlorate (AgClO4) and 5-(imidazol-1-ylmethyl)isophthalic acid. The complexes have been characterized by single-crystal and powder X-ray diffraction, IR spectroscopy, and elemental analyses. In 1–...
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